Synthesis of Yb nanoparticles by laser ablation of ytterbium target in sodium bis(2-ethylhexyl)sulfosuccinate reverse micellar solution

Surfactant-coated ytterbium nanoparticles were produced by Nd:YAG laser ablation of a Yb bulk target immersed in sodium bis(2-ethylhexyl)sulfosuccinate (AOT)/n-heptane micellar solution. In our experimental conditions, as highlighted by IR spectroscopy, AOT molecules are not decomposed by the intense laser pulses but play a pivotal role in the stabilisation of Yb nanoparticles. The formation of Yb nanoparticles in the liquid phase was monitored by UV-Vis spectroscopy whereas the Yb/AOT composites obtained by evaporation of the organic solvent were characterised by XPS and TEM. Data analysis consistently shows the presence of surfactant-coated, nearly spherical and non-interacting Yb nanoparticles of mean diameter of 3 nm.Moreover, the presence of bigger polycrystalline nanoparticles (about 30%) in coexistence with smaller mono crystalline ones indicates that, after the rapid formation of the pristine Yb nanoparticles from plume condensation, two processes effectively compete for their size distribution: nanoparticle agglomeration and surfactant adsorption.     

Acrylamide formation and colour development in low-fat baked potato products as influenced by baking conditions and oil type

The objective of this study was to investigate the effect of oil type and oxidation status on acrylamide (AA) formation and colour development in potato products under domestic baking conditions. Sunflower, soybean and olive oil were used; the first one was thermally oxidized to obtain different oxidation status. A potato dough containing 10 % oil, potato powder, flour and water was shaped into thin discs and baked at 180 °C for different heating times. AA concentration, moisture content and surface colour were determined. Results obtained showed that neither the nature of lipids present, in terms of content of unsaturated fatty acids, nor the degree of fat oxidation influenced AA formation in low-fat baked potato products. Browning ratio higher than 45 % and moisture content lower than 17 % resulted in dark brown, almost burnt, products. Moreover, in those cases, no correlation could be found between those variables and AA content, since formation and degradation simultaneously occur. When the browning ratio ranged between 0 and 45 %, a good linear correlation with AA formation was observed, suggesting that the browning ratio may be considered as a reliable indicator of AA concentration. Finally, AA less than 1000 μg/kg, which is an indicative value that has been recently set for potato crisps by the European Commission, corresponds to a browning ratio of less than 8 % and moisture content more than 23.5 %.     

Profiling selected phytochemicals and nutrients in different tissues of the multipurpose tree Moringa oleifera L., grown in Ghana

The purpose of this new study was to determine the types and levels of major phytochemicals (non-nutrients) and nutrients in the different tissues from vegetative and flowering Moringa oleifera L. an important multipurpose crop. Rhamnose and acetyl-rhamnose-substituted glucosinolates were found in all of the M. oleifera tissues with different profiles depending on the tissue. In addition the tissues of M. oleifera had a relatively complex flavonoid profile consisting of glucosides, rutinosides, malonylglucosides and traces of acetylglucosides of kaempferol, quercetin and isorhamnetin. Fatty acid profiling of the different tissues showed that leaves were rich in palmitic (16:0) and linolenic (18:3) acid whereas seeds were predominated by oleic acid (18:1). Roots were rich in palmitic and oleic acid, whereas stems and twigs predominately contained palmitic acid. Potassium, magnesium and calcium were the predominant minerals in all of the tissues. Low levels of selenium were detected only in whole seeds.     

Ester-functionalized poly(3-alkylthiophene) copolymers: Synthesis,physicochemical characterization and performance in bulk heterojunction organic solar cells

The introduction of functional moieties in the donor polymer (side chains) offers a potential pathway toward selective modification of the nanomorphology of conjugated polymer:fullerene active layer blends applied in bulk heterojunction organic photovoltaics, pursuing morphology control and solar cell stability. For this purpose, two types of poly(3-alkylthiophene) random copolymers, incorporating different amounts (10/30/50%) of ester-functionalized side chains, were efficiently synthesized using the Rieke method. The solar cell performance of the functionalized copolymers was evaluated and compared to the pristine P3HT:PCBM system. It was observed that the physicochemical and opto-electronic characteristics of the polythiophene donor material can be modified to a certain extent via copolymerization without (too much) jeopardizing the OPV efficiency, as far as the functionalized side chains are introduced in a moderate ratio (<30%) and that preference is given to side chains with a small molar volume. A range of complementary techniques – UV–Vis spectroscopy, (modulated temperature) differential scanning calorimetry, transmission electron microscopy and X-ray diffraction analysis – indicated that variations in polymer crystallinity, while maintaining a high level of regioregularity, are probably the main factor responsible for the observed differences.     

Arginine dihydrolase pathway in Lactobacillus plantarum from orange.

Lactobacillus plantarum N8 and N4 strains isolated from orange degraded L-arginine to citrulline, ornithine and ammonia. Citrulline and ornithine were consumed. Lactobacillus plantarum N4 utilized arginine and ornithine to a higher extent than Lactobacillus plantarum N8. Urea was not detected during arginine degradation, indicating that the amino acid degradation was carried out only by the arginine dihydrolase pathway. Citrulline increased the growth of the two strains, arginine only increased the growth of Lactobacillus plantarum N4. Ornithine did not modify the growth of the strains studied. With different behavior, Lactobacillus plantarum N8 and N4 strains were able to derive energy and ammonia from arginine or citrulline catabolism. This is interesting for microorganisms developing in a stressful environment.     

Performance comparison between partial oxidation and methane steam reforming processes for solid oxide fuel cell (SOFC) micro combined heat and power (CHP) system

The aim of this research work is to describe in qualitative and quantitative form the performance of a micro Combined Heat and Power system for residential application based on Solid Oxide Fuel Cell fueled by natural gas with two different types of pre-reforming systems, namely Steam Reforming and Partial Oxidation and recirculation of anode and cathode gas.The comparative analysis among the different configurations will lead us to conclude that maximum efficiency is achieved when cathode and anode gas recirculation are used along with steam methane reforming. Further Steam Methane Reforming process produces a higher electrical system efficiency compared to Partial oxidation reforming process.Efficiency is affected when running the system in part load mode mainly due to heat loss, additional natural gas supplied to the burner to satisfy the required heat demand inside the system, and ejector efficiency drop in the recirculation system. Due to high temperature of operation heat loss strongly affects the system efficiency especially at part load operation.     

Calculation procedure of the shading factor under complex boundary conditions

Together with the evolution of buildings and systems, energy assessment models have become more and more detailed, requiring a precise evaluation of the building loads and gains.For an accurate analysis of solar heat gains, technical standards introduce an external shading reduction coefficient of the incident solar radiation, called shading factor. Its value is provided for simple geometries, which are usually not suitable to properly describe a real environment. In addition, the relations adopted to evaluate the shading factor are based on simplified hypotheses, which cause non-negligible errors when compared to more complex algorithms.The objective of this study is the development of a calculation procedure of the shading factor under complex boundary conditions. The algorithms have been implemented in a software tool written in Matlab language. It can provide for the value of the shading factor on a generically oriented and tilted surface. After setting the site and the time for the simulation, generic-shaped windows can be modelled. The external environment, which can be imported from DXF files, can include a horizon profile, generic-shaped obstructions and vegetation. The calculation can be performed for every sky condition: clear, average or generic. In addition, the simulation can be run to obtain instantaneous, daily average or monthly average shading factor values.     

Automatic end-of-line tuning for a motion inverter in agricultural tractors

End-of-line tuning is a crucial step for any mass-produced system endowed with automatic controllers. As a matter of fact, due to components tolerances and spreads in the production line, the controller tuning performed on a prototype system is never optimal on the final product. In many industrial applications, though, the end-of-line tuning is performed by human testers, and this does not always guarantee an objective assessment of the closed-loop system quality. This paper proposes a systematic way to design an automatic tuning procedure for a motion-inverter controller in agricultural tractors, which allows to significantly reduce the costs of end-of-line tuning and to obtain a homogeneous manoeuvre quality in all vehicles. The proposed automatic tuning system adapts the controller parameters governing the open-loop phase of the manoeuvre until a predefined manoeuvre quality is achieved. The parameters adaptation phase is guided by an on-line objective assessment of the manoeuvre quality from measured data, which allows to automatically classify the performed manoeuvre with respect to its quality attributes. The effectiveness of the proposed approach is assessed on a prototype vehicle.